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Obi,
The big thing when trying match a color exactly is to make sure you have your final lighting setup, as the color/quality of your light can completely change the look of your colors.
Since you just posted viewport shots I will just add, to make sure that you are rendering your building, as the viewport is not a true representation of the final colors.
The last thing that may help, based on your posted images, is to change the setting on your Color Chooser from [0 to 1] to [0 to 255]...depending on the range of your numbers.
You had entered 120, 36, 77 and you got white because your range was still set to [0 to 1]
Matching colors is all about your eyes and the color calabration of your monitor...so it will be a constant struggle. Just keep rendering and tweaking...and have fun.
~Ben
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